The widespread use of lithium-ion batteries in electric vehicles and electronics increases demand for better recycling. Rice University researchers developed a two-step flash Joule heating-chlorination and oxidation process (FJH-ClO) that replaces lengthy wet chemical treatments with brief, controlled thermal and gas reactions. The team reports the results in Advanced Materials.
In the first step, materials from spent batteries are heated briefly in chlorine gas. This treatment breaks down the compounds that bind lithium and transition metals. In the second step, a short heating in air converts most metals into oxidized forms that can be separated from lithium. Because lithium resists oxidation, it stays as a chloride and is removed with water. The approach is acid-free and uses fast, controllable reactions.
Laboratory tests show recovery of nearly all valuable materials with high purity, including lithium, cobalt and graphite. Early analyses indicate the process may require about half as much energy, use 95% fewer chemicals, and lower costs compared with existing methods. The researchers say the method reduces energy use, chemical consumption, and wastewater, and avoids harsh acids common in conventional recycling. The team plans to scale the process through their startup, Flash Metals USA (a division of Metallium Ltd.), aiming to support large-scale recovery and reduce reliance on virgin mining. Funding came from the Defense Advanced Research Projects Agency, the Air Force Office of Scientific Research, and the US Army Corps of Engineers.
Difficult words
- flash Joule heating — very rapid heating using electric current
- chlorination — treatment using chlorine gas to react
- oxidation — chemical reaction that adds oxygen or removes electrons
- transition metal — metal often used in batteries and electronicstransition metals
- acid-free — not using strong acids in the process
- purity — degree to which a material is free of impurities
- wastewater — used water produced by industrial or laboratory processes
Tip: hover, focus or tap highlighted words in the article to see quick definitions while you read or listen.
Discussion questions
- How might reducing chemical consumption and wastewater from recycling affect local communities and the environment?
- What technical or economic challenges could arise when scaling this flash Joule heating-chlorination and oxidation process to industrial levels?
- If this process reduces reliance on virgin mining, how could that change the supply chain for batteries and electronics?
